– The cause for efficiency degradation in an actual operating environment has been identified, with proposal of material processing method for improving performance stability
– Expected to significantly contribute to the further commercialization of next generation quantum dot PV devices
A technology to further accelerate the commercialization of Colloidal Quantum Dot(CQD) Photovoltaic(PV) devices, which are expected to be next-generation photovoltaic devices, has been developed.
On the 30th (Monday), DGIST announced that a research team of Professor Jongmin Choi from the Department of Energy Science & Engineering t and Professor Edward H. Sargent from the University of Toronto has identified the cause of the performance degradation in CQD PV devices and developed a material processing method capable of stabilizing the performance of the devices.
Quantum dots have excellent light absorbance and are capable of absorbing light over a wide range of wavelengths. Hence, they have gained expectation as a key material for the next generation photovoltaic devices. In particular, quantum dots are light, flexible, and involve low processing costs; therefore, they can be replaced by supplementing the drawbacks of silicon solar cells currently in use
In this regard, several studies on photoelectric conversion efficiency (PCE) have been conducted with the aim of improving the performance of CQD PV devices. However, very few studies have focused on improving the stability of these devices, which is necessary for the commercialization process. In particular, few studies have used the CQD PV device at the Maximum Power Point, which is the actual operating environment of PV devices.
For this purpose, the research team investigated the causes of performance degradation by continuously exposing them to illumination and oxygen for long periods of time, similar to the actual operating conditions, in order to improve the stability required for the actual commercialization stage of CQD PV devices. As a result, it was identified that the iodine ions on the surface of the quantum dot solids were removed via oxidation, resulting in the formation of an oxide layer. This oxide layer resulted in the deformation of the quantum dot structure, thereby decreasing the efficiency of the device.
The research team developed a ligand substitution method with potassium(K) to improve the low efficiency of the device. Ligand refers to the ions or molecules that bond to the central atom of a complex similar to a branch. Here, potassium iodide, which prevents the oxidation of iodine, was deployed on the surface of quantum dot solids to undergo a substitution process. As a result of application of the invented method, the device maintained its continuous performance rate of over 80%, which is its initial efficiency rate, for 300 hours. This number is a figure that is higher than premeasured performance thus far.
Professor Jongmin Choi from DGIST said, “The study is to demonstrate that the CQD PV device can operate more stably in the actual operating environment,” and further commented, “The results are expected to further accelerate the commercialization of the CQD PV device. ”
The results of this study were published on February 20, in a world-leading, international academic journal Advanced Materials (IF = 25.809). Professor Jongmin Choi from the Energy Science & Engineering Department of DGIST participated in this study as the lead author.
Reference: Jongmin Choi, Min-Jae Choi, Junghwan Kim, Filip Dinic, Petar Todorovic, Bin Sun, Mingyang Wei, Se-Woong Baek, Sjoerd Hoogland, F. Pelayo García de Arquer, Oleksandr Voznyy, and Edward H. Sargent, “Stabilizing Surface Passivation Enables Stable Operation of Colloidal Quantum Dot Photovoltaic Devices at Maximum Power Point in an Air Ambient“, Advanced Materials, on 13 January 2020.